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Experimental Techniques

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Apparatus for Measurements

  • Time is measured with a stopwatch or stopclock, accurate to one or two decimal places; units are seconds or minutes.
  • Temperature is measured with a thermometer (precision ±0.5 °C) or digital temperature probe (precision ±0.1 °C); units are degrees Celsius (°C).
  • Mass is measured using a digital balance (usually to two decimal places); balance must be tared before use and allowed to settle.
  • Volume of liquid is measured with burettes (most accurate for variable volumes, 0–50 cm³), volumetric pipettes (most accurate for fixed volumes, e.g. 10 cm³ or 25 cm³), or measuring cylinders (for approximate volumes).
  • Volume of gas is measured using a gas syringe (more precise) or by downward displacement of water (not suitable for soluble gases).
  • When reading a burette, read from the bottom of the meniscus; the scale runs from 0.00 cm³ at the top to 50.00 cm³ at the bottom.

Apparatus for measuring volume

Apparatus for measuring volume

Solutions

  • Solvent: the liquid in which a solute dissolves (e.g. water in seawater).
  • Solute: the substance that dissolves in a solvent (e.g. salt in seawater).
  • Solution: the mixture formed when a solute dissolves in a solvent (e.g. seawater).
  • Saturated solution: contains the maximum concentration of solute dissolved at a given temperature.
  • Soluble substances dissolve; insoluble substances do not dissolve.
  • Filtrate: the liquid that passes through a filter; residue: the solid left behind after filtration or evaporation.

Acid-Base Titrations

  • Titration determines the concentration of an acid or alkali by neutralisation; can also be used to prepare salts.
  • Apparatus: 25 cm³ volumetric pipette, pipette filler, 50 cm³ burette, 250 cm³ conical flask, funnel, indicator, clamp stand, white tile.
  • Method: pipette a fixed volume of alkali into a conical flask, add indicator, then add acid from the burette while swirling until the endpoint (sharp colour change).
  • Record burette readings to the nearest 0.05 cm³; repeat until two concordant results (within 0.1 cm³) are obtained.
  • Common indicators: methyl orange (red in acid, yellow in alkali, orange at endpoint) and phenolphthalein (colourless in acid, pink in alkali).
  • Common errors: not removing the funnel from the burette, not filling the jet space, and reading the burette from the top of the meniscus.

Titration apparatus set-up

Titration apparatus set-up

Folien

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Übungsfragen

Gratis-Vorschau — 8 von 48 Fragen. Registriere dich, um alle zu sehen.
  1. 1.Which piece of apparatus is most accurate for measuring a variable volume of liquid between 0 and 50 cm³?

    Easy
    • AMeasuring cylinder
    • BBurette
    • CVolumetric pipette
    • DGas syringe
  2. 2.A volumetric pipette is used to measure a fixed volume of liquid accurately.

    Easy

    True or false?

  3. 3.A stopwatch displays 1:30 (minutes:seconds). What is the time in seconds?

    Easy
    • A99
    • B81
    • C90
    • D108
  4. 4.Complete the sentence about titration.

    Easy

    The endpoint is reached when one drop causes a sharp ____ change.

  5. 5.Match each indicator to its colour in acid.

    Medium
    • Methyl orange
    • Phenolphthalein
    • Litmus
    • Red
    • Colourless
    • Red
  6. 6.Arrange the following steps in a titration in the correct order.

    Medium
    • Add indicator to conical flask
    • Fill burette with acid
    • Record initial burette reading
    • Perform rough titration
  7. 7.Which of the following is the most accurate way to measure a fixed volume of liquid?

    Easy
    • AMeasuring cylinder
    • BBurette
    • CVolumetric pipette
    • DBeaker
  8. 8.What term describes a solution that contains the maximum concentration of solute at a given temperature?

    Easy

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