Reactions of alkenes and alcohols
Apréndelo jugando
Responde estas preguntas para ganar energía, luego pesca y explora. Sin cuenta.
Apuntes de la lección
Alkene Structure and Formulae
- Alkenes are hydrocarbons that contain a carbon-carbon double bond (C=C).
- The C=C double bond is the functional group of alkenes and is responsible for their characteristic reactions.
- The general formula of the alkene homologous series is CnH2n.
- The first four alkenes are ethene (C2H4), propene (C3H6), butene (C4H8) and pentene (C5H10).
- Alkenes are unsaturated compounds because they contain two fewer hydrogen atoms than the alkane with the same number of carbon atoms.
- The position of the double bond can be shown by a number, e.g. but-1-ene has the C=C starting at carbon 1.
- Alkenes are more reactive than alkanes because the C=C bond can open up to form single bonds, allowing other atoms to attach.
Combustion of Alkenes
- Alkenes undergo complete and incomplete combustion in air.
- Because alkenes have a higher carbon to hydrogen ratio, they tend to undergo incomplete combustion, producing a smoky flame.
- Complete combustion occurs with excess oxygen and produces carbon dioxide and water.
- Example: butene + oxygen → carbon dioxide + water.
- Incomplete combustion occurs with insufficient oxygen and can produce carbon monoxide and/or carbon (soot) along with water.
- Example: butene + oxygen → carbon monoxide + water, or butene + oxygen → carbon + water.
- Smoky yellow flames indicate a higher carbon to hydrogen ratio in the molecule.
Addition Reactions of Alkenes
- Alkenes mainly undergo addition reactions, in which atoms of a simple molecule add across the C=C double bond.
- The double bond opens up to form a single bond, allowing two more atoms to bond, one on each carbon.
- A saturated compound is formed when an alkene undergoes an addition reaction.
- Hydrogenation: alkenes react with hydrogen at 150 °C using a nickel catalyst to form an alkane.
- Hydrogenation is used to make margarine from vegetable oils by partially hydrogenating polyunsaturated oils to increase Mr and turn them into solid fats.
- Hydration: alkenes react with steam at around 330 °C and 60–70 atm using a concentrated phosphoric acid catalyst to form an alcohol.
- Halogenation: alkenes react readily with halogens at room temperature, with halogen atoms adding across the C=C bond.
- The bromine water test: bromine water is an orange-yellow solution; when shaken with an alkene, the colour is decolourised (turns colourless) because an addition reaction occurs.
Alcohols: Structure and Uses
- All alcohols contain the hydroxyl (-OH) functional group.
- The first four alcohols are methanol (CH3OH), ethanol (C2H5OH), propanol (C3H7OH) and butanol (C4H9OH).
- Alcohols are named using the alkane name with the final 'e' replaced by 'ol'.
- Alcohols are colourless liquids that dissolve in water to form neutral solutions.
- The first four alcohols are commonly used as fuels.
- Methanol and ethanol are used as solvents because they dissolve many substances that water cannot, such as fats and oils.
- Ethanol is the alcohol found in alcoholic drinks and is also used as a fuel for vehicles.
Reactions of Alcohols
- Alcohols undergo combustion to form carbon dioxide and water; e.g. ethanol + oxygen → carbon dioxide + water.
- Alcohols react with sodium metal to produce hydrogen gas and a metal salt (e.g. sodium + methanol → sodium methoxide + hydrogen).
- Alcohols can be oxidised to produce carboxylic acids.
- When ethanol is heated with acidified potassium dichromate, it oxidises to ethanoic acid; the solution turns from orange to green.
- The oxidation of ethanol in wine left open to air produces ethanoic acid, giving a vinegary taste.
Production of Ethanol by Fermentation
- Ethanol can be produced by fermentation: sugar or starch is dissolved in water and yeast is added.
- Fermentation takes place between 15 and 35 °C in the absence of oxygen for a few days.
- Yeast contains enzymes that break down sugar to alcohol; if too cold the reaction is slow, if too hot the enzymes are denatured.
- The yeast respires anaerobically: glucose → carbon dioxide + ethanol.
- Yeast is killed once the alcohol concentration reaches about 15%, so the vessel is emptied and the process restarted — this makes fermentation a batch process.
- Fermentation produces a dilute ethanol solution; fractional distillation is used to separate ethanol (boiling point 78 °C) from water (100 °C).
Carboxylic Acids: Structure and Reactions
- Carboxylic acids contain the -COOH functional group.
- The first four carboxylic acids are methanoic acid, ethanoic acid, propanoic acid and butanoic acid.
- They are named using the alkane name with the final 'e' replaced by 'oic acid'.
- Carboxylic acids are soluble in water, forming weakly acidic solutions.
- They react with carbonates to produce a metal salt, water and carbon dioxide gas.
- They react with alcohols in the presence of an acid catalyst (concentrated sulfuric acid) to form esters — this is esterification.
- Esters have the functional group R-COO-R; they are sweet-smelling oily liquids used in flavourings and perfumes, and are volatile.
- Example: ethanoic acid + ethanol → ethyl ethanoate + water.
Carboxylic Acids as Weak Acids (HT only)
- Carboxylic acids show typical acid reactions but are weak acids.
- They dissolve in water but only partially ionise, producing solutions with pH between 3 and 7.
- They form an equilibrium with their ions, but most molecules remain undissociated.
- Ethanoic acid is about 95% undissociated — only about 5 out of 100 molecules ionise.
- Because they are weak, their reactions are often slow or barely noticeable at room temperature.
Diapositivas
Sign up free to view the lesson slides
Step through every slide for this topic — plus flashcards and revision notes — with a free account.
Preguntas de práctica
Vista previa gratis — 8 de 67 preguntas. Regístrate para verlas todas.
1.Which statement correctly describes alkenes?
Easy- AAlkenes are saturated hydrocarbons
- BAlkenes are unsaturated hydrocarbons
- CAlkenes contain hydrogen, carbon and oxygen atoms
- DAlkenes contain only single carbon-carbon bonds
2.What is the correct general formula of an alkene?
Easy- ACnH2n+2
- BCnH2n
- CCnH2n+1OH
- DCnH2n+1COOH
3.What is the correct general formula of an alcohol?
Easy- ACnH2n+2
- BCnH2n
- CCnH2n+1OH
- DCnH2n+1COOH
4.The functional group in alcohols is the hydroxyl group, -OH.
EasyTrue or false?
5.Bromine water is decolourised when shaken with an alkane.
EasyTrue or false?
6.Which of the following is the molecular formula of ethene?
Easy- AC2H6
- BC2H4
- CC3H6
- DCH4
7.Which of the following is the molecular formula of ethanol?
Easy- ACH3OH
- BC2H5OH
- CC3H7OH
- DC2H4
8.What type of reaction takes place between ethene and bromine?
Medium- ASubstitution
- BAddition
- CCombustion
- DNeutralisation
Unlock all 67 questions, flashcards & more
Crea una cuenta gratis para ver todas las preguntas, las diapositivas, las tarjetas y los apuntes de repaso de este tema.