Group Properties & Trends
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Notes
Group I (Alkali Metals) – Physical Properties
- Group I metals are called **alkali metals** because they form alkaline solutions with water.
- They are **soft** and can be cut with a knife; softness increases down the group.
- Freshly cut surfaces are **shiny and silvery**.
- They have **low melting points** (some melt on a hot day) and **low densities** compared to other metals.
- Melting point **decreases** down the group; density generally **increases** (with an early exception).
- They are good conductors of heat and electricity.
Group I – Chemical Properties & Reactivity
- All have **one electron in their outer shell**, which they readily lose to form +1 ions.
- They react vigorously with water: **2M(s) + 2H₂O(l) → 2MOH(aq) + H₂(g)**.
- Reactivity **increases** down the group (Li < Na < K < Rb < Cs < Fr).
- Lithium: fizzes, moves on surface; Sodium: more vigorous, melts into a ball; Potassium: burns with a **lilac flame**.
- They react with oxygen and water vapour in air, so are **stored under oil**.
- Rubidium and caesium react explosively with water; francium is extremely reactive but rare/radioactive.
Group VII (Halogens) – Physical Properties
- Halogens are **diatomic** non-metals (F₂, Cl₂, Br₂, I₂, At₂).
- All have **seven electrons in their outer shell** and gain one electron to form halide ions.
- At room temperature: chlorine is a **pale yellow-green gas**, bromine is a **red-brown liquid**, iodine is a **grey-black solid**.
- Melting and boiling points **increase** down the group; density also increases.
- Colour **darkens** down the group: fluorine (yellow), chlorine (pale green), bromine (red-brown), iodine (grey-black), astatine (black).
- Aqueous solutions: chlorine (very pale green, often colourless), bromine (orange/yellow), iodine (brown).
Group VII – Reactivity & Displacement Reactions
- Reactivity **decreases** down the group (opposite to Group I).
- A more reactive halogen **displaces** a less reactive halogen from its halide solution.
- Chlorine displaces bromine from KBr: **2KBr(aq) + Cl₂(aq) → 2KCl(aq) + Br₂(aq)** (orange colour).
- Chlorine displaces iodine from KI: brown colour of iodine appears.
- Bromine displaces iodine from KI: brown colour of iodine appears.
- No reaction occurs if the halogen is less reactive than the halide (e.g., iodine + KCl).
Transition Elements
- Transition elements are metals found in the centre of the Periodic Table (between Group 2 and 3).
- They are **hard, strong, lustrous**, and conduct heat and electricity; most have **high melting points** (except mercury).
- They **form ions with different charges** (e.g., Fe²⁺ and Fe³⁺) and have **variable oxidation states**.
- They form **coloured compounds** (e.g., copper sulfate is blue, copper oxide is black).
- They are useful as **catalysts** (e.g., iron in the Haber process).
- Scandium and zinc are not considered transition elements as they have only one oxidation state and form colourless compounds.
Noble Gases
- Noble gases are in **Group VIII**; they are **monatomic**, colourless gases at room temperature.
- They have **very low melting and boiling points** and are **unreactive (inert)**.
- Inertness is due to their **full outer electron shells** (e.g., He: 2, Ne: 2,8, Ar: 2,8,8).
- Full outer shells mean they have no tendency to gain, lose, or share electrons.
- They are used in lighting (neon signs) and as inert atmospheres (argon in welding).
Trends Summary
- Group I: reactivity increases down; melting point decreases; density increases (with early exception).
- Group VII: reactivity decreases down; melting/boiling point increases; colour darkens; density increases.
- Noble gases: all are unreactive; boiling points increase down the group (He lowest, Rn highest).
- Transition elements: high melting points, variable oxidation states, coloured compounds, catalytic activity.
Bohr model of sodium (Group I) showing one outer electron.
Bohr model of chlorine (Group VII) showing seven outer electrons.
Practice questions
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1.How many electrons are in the outer shell of a Group I metal atom?
Easy- A1
- B2
- C7
- D8
2.Which of the following is a physical property of Group I metals?
Easy- AThey are hard and strong
- BThey have high melting points
- CThey are soft and easy to cut
- DThey are gases at room temperature
3.What is the trend in reactivity of Group I metals as you go down the group?
Easy- AReactivity decreases
- BReactivity increases
- CReactivity stays the same
- DReactivity first increases then decreases
4.Which halogen is a red-brown liquid at room temperature?
Easy- AChlorine
- BBromine
- CIodine
- DFluorine
5.What is the trend in reactivity of Group VII elements as you go down the group?
Easy- AReactivity increases
- BReactivity decreases
- CReactivity stays the same
- DReactivity first decreases then increases
6.When chlorine water is added to potassium bromide solution, what colour change is observed?
Medium- AColourless to brown
- BColourless to orange
- COrange to colourless
- DBrown to colourless
7.Which of the following is a characteristic property of transition elements?
Medium- AThey form colourless compounds
- BThey have only one oxidation state
- CThey form coloured compounds
- DThey are gases at room temperature
8.Why are noble gases unreactive?
Medium- AThey have a full outer shell of electrons
- BThey have one electron in their outer shell
- CThey are diatomic molecules
- DThey have low melting points
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