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Group Properties & Trends

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Notes

Group I (Alkali Metals) – Physical Properties

  • Group I metals are called **alkali metals** because they form alkaline solutions with water.
  • They are **soft** and can be cut with a knife; softness increases down the group.
  • Freshly cut surfaces are **shiny and silvery**.
  • They have **low melting points** (some melt on a hot day) and **low densities** compared to other metals.
  • Melting point **decreases** down the group; density generally **increases** (with an early exception).
  • They are good conductors of heat and electricity.

Group I – Chemical Properties & Reactivity

  • All have **one electron in their outer shell**, which they readily lose to form +1 ions.
  • They react vigorously with water: **2M(s) + 2H₂O(l) → 2MOH(aq) + H₂(g)**.
  • Reactivity **increases** down the group (Li < Na < K < Rb < Cs < Fr).
  • Lithium: fizzes, moves on surface; Sodium: more vigorous, melts into a ball; Potassium: burns with a **lilac flame**.
  • They react with oxygen and water vapour in air, so are **stored under oil**.
  • Rubidium and caesium react explosively with water; francium is extremely reactive but rare/radioactive.

Group VII (Halogens) – Physical Properties

  • Halogens are **diatomic** non-metals (F₂, Cl₂, Br₂, I₂, At₂).
  • All have **seven electrons in their outer shell** and gain one electron to form halide ions.
  • At room temperature: chlorine is a **pale yellow-green gas**, bromine is a **red-brown liquid**, iodine is a **grey-black solid**.
  • Melting and boiling points **increase** down the group; density also increases.
  • Colour **darkens** down the group: fluorine (yellow), chlorine (pale green), bromine (red-brown), iodine (grey-black), astatine (black).
  • Aqueous solutions: chlorine (very pale green, often colourless), bromine (orange/yellow), iodine (brown).

Group VII – Reactivity & Displacement Reactions

  • Reactivity **decreases** down the group (opposite to Group I).
  • A more reactive halogen **displaces** a less reactive halogen from its halide solution.
  • Chlorine displaces bromine from KBr: **2KBr(aq) + Cl₂(aq) → 2KCl(aq) + Br₂(aq)** (orange colour).
  • Chlorine displaces iodine from KI: brown colour of iodine appears.
  • Bromine displaces iodine from KI: brown colour of iodine appears.
  • No reaction occurs if the halogen is less reactive than the halide (e.g., iodine + KCl).

Transition Elements

  • Transition elements are metals found in the centre of the Periodic Table (between Group 2 and 3).
  • They are **hard, strong, lustrous**, and conduct heat and electricity; most have **high melting points** (except mercury).
  • They **form ions with different charges** (e.g., Fe²⁺ and Fe³⁺) and have **variable oxidation states**.
  • They form **coloured compounds** (e.g., copper sulfate is blue, copper oxide is black).
  • They are useful as **catalysts** (e.g., iron in the Haber process).
  • Scandium and zinc are not considered transition elements as they have only one oxidation state and form colourless compounds.

Noble Gases

  • Noble gases are in **Group VIII**; they are **monatomic**, colourless gases at room temperature.
  • They have **very low melting and boiling points** and are **unreactive (inert)**.
  • Inertness is due to their **full outer electron shells** (e.g., He: 2, Ne: 2,8, Ar: 2,8,8).
  • Full outer shells mean they have no tendency to gain, lose, or share electrons.
  • They are used in lighting (neon signs) and as inert atmospheres (argon in welding).

Trends Summary

  • Group I: reactivity increases down; melting point decreases; density increases (with early exception).
  • Group VII: reactivity decreases down; melting/boiling point increases; colour darkens; density increases.
  • Noble gases: all are unreactive; boiling points increase down the group (He lowest, Rn highest).
  • Transition elements: high melting points, variable oxidation states, coloured compounds, catalytic activity.

Bohr model of sodium (Group I) showing one outer electron.

Na — Bohr model (2,8,1)11p12n

Bohr model of chlorine (Group VII) showing seven outer electrons.

Cl — Bohr model (2,8,7)17p18n

Practice questions

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  1. 1.How many electrons are in the outer shell of a Group I metal atom?

    Easy
    • A1
    • B2
    • C7
    • D8
  2. 2.Which of the following is a physical property of Group I metals?

    Easy
    • AThey are hard and strong
    • BThey have high melting points
    • CThey are soft and easy to cut
    • DThey are gases at room temperature
  3. 3.What is the trend in reactivity of Group I metals as you go down the group?

    Easy
    • AReactivity decreases
    • BReactivity increases
    • CReactivity stays the same
    • DReactivity first increases then decreases
  4. 4.Which halogen is a red-brown liquid at room temperature?

    Easy
    • AChlorine
    • BBromine
    • CIodine
    • DFluorine
  5. 5.What is the trend in reactivity of Group VII elements as you go down the group?

    Easy
    • AReactivity increases
    • BReactivity decreases
    • CReactivity stays the same
    • DReactivity first decreases then increases
  6. 6.When chlorine water is added to potassium bromide solution, what colour change is observed?

    Medium
    • AColourless to brown
    • BColourless to orange
    • COrange to colourless
    • DBrown to colourless
  7. 7.Which of the following is a characteristic property of transition elements?

    Medium
    • AThey form colourless compounds
    • BThey have only one oxidation state
    • CThey form coloured compounds
    • DThey are gases at room temperature
  8. 8.Why are noble gases unreactive?

    Medium
    • AThey have a full outer shell of electrons
    • BThey have one electron in their outer shell
    • CThey are diatomic molecules
    • DThey have low melting points

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