Covalent molecules and their properties

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Big idea: covalent molecules and their properties

  • Key concept: Systems. Atoms share electron pairs in covalent bonds. Melting a simple molecular substance overcomes intermolecular attractions, not the covalent bonds within each molecule.
  • Related concepts: Models and evidence. Use a scientific explanation to make predictions, then test it against observations.
  • Global context: Scientific and technical innovation. Molecular properties help select solvents and fuels.

Covalent Bonds

  • A covalent bond is formed when pairs of electrons are shared between atoms.
  • Only non-metal elements participate in covalent bonding.
  • Each atom gains a full outer shell of electrons (noble gas configuration).
  • Covalently bonded substances may consist of small molecules or giant molecules.
  • Dot-and-cross diagrams show the electronic configuration: dots for one atom's electrons, crosses for the other's.
  • Electron shells overlap and shared electrons are shown in the overlap region.

A single covalent bond in hydrogen

A single covalent bond in hydrogen

Single Covalent Bonds

  • A single covalent bond involves one shared pair of electrons.
  • Examples: H₂ (H–H), Cl₂ (Cl–Cl), H₂O, CH₄, NH₃, HCl.
  • In H₂O, oxygen shares one electron with each hydrogen atom, forming two single bonds.
  • In CH₄, carbon shares one electron with each of four hydrogen atoms.
  • In NH₃, nitrogen shares one electron with each of three hydrogen atoms.
  • In HCl, hydrogen and chlorine share one pair of electrons.

Double and Triple Covalent Bonds

  • Some atoms share two pairs of electrons to form a double bond.
  • Some atoms share three pairs of electrons to form a triple bond.
  • O₂ has a double bond (O=O) – each oxygen shares two electrons.
  • N₂ has a triple bond (N≡N) – each nitrogen shares three electrons.
  • Ethene (C₂H₄) has a double bond between the two carbon atoms.
  • Carbon dioxide (CO₂) has two double bonds (O=C=O).

A double covalent bond in oxygen

A double covalent bond in oxygen

Properties of Simple Molecular Compounds

  • Simple molecular compounds have low melting and boiling points.
  • They are usually liquids or gases at room temperature.
  • As molecule size increases, melting and boiling points increase.
  • They have poor electrical conductivity – do not conduct in solid or liquid state.
  • They are insulators (e.g., plastic coating on wires).

Explaining Properties

  • Atoms within molecules are held by strong covalent bonds.
  • Between molecules there are weak intermolecular forces.
  • Low melting/boiling points are due to weak intermolecular forces requiring little energy to overcome.
  • Intermolecular forces are about one tenth as strong as covalent bonds.
  • Larger molecules have more electrons, increasing intermolecular forces and raising melting/boiling points.
  • Poor conductivity because there are no free ions or electrons to carry charge.

Bonds within and between water molecules

Bonds within and between water molecules

Distinguishing Covalent from Ionic

  • Covalent compounds contain only non-metals.
  • Ionic compounds contain metal and non-metal.
  • In dot-and-cross diagrams, covalent compounds show overlapping shells with shared electrons.
  • Ionic compounds show separate ions with square brackets and charges.
  • Covalent compounds have low melting points; ionic compounds have high melting points.

Think like a scientist

  • Use teacher-provided melting-point and conductivity data to compare several simple molecular substances.
  • Comparison: the molecular substance being compared. Outcome: melting point and electrical conductivity.
  • Control: compare measurements made under the same pressure. Explain why this makes the comparison fairer.
  • Evidence: Use a consistent method, repeated observations where appropriate and a table with labelled quantities and units. Keep unexpected results and investigate their cause.
  • Safety: Practical activities need teacher supervision and an appropriate risk assessment. Use the provided data or simulation where the investigation specifies it.
  • Inquiry task: State a testable question, predict the outcome using the science, then explain how your observations would support or challenge the prediction.

Evaluate the science

  • Molecular properties help select solvents and fuels.
  • A material's melting point alone does not establish its bonding type; several lines of evidence are needed.
  • Evaluation task: Link your conclusion to evidence, identify a limitation and suggest a specific improvement. Distinguish a measured result from an explanation of its cause.

Slide

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Câu hỏi luyện tập

Xem trước miễn phí — 8 trên 52 câu hỏi. Đăng ký để xem tất cả.
  1. 1.What type of bonding is found in methane?

    Easy
    • ACovalent
    • BIonic
    • CMetallic
    • DHydrogen bonding
  2. 2.Which of the following substances has a simple molecular structure?

    Easy
    • ACarbon dioxide
    • BCalcium carbonate
    • CCopper
    • DMagnesium oxide
  3. 3.A covalent bond is formed when two atoms:

    Easy
    • AShare a pair of electrons
    • BTransfer electrons
    • CShare protons
    • DAttract via opposite charges
  4. 4.When a simple molecular substance melts, what is broken?

    Easy
    • AIntermolecular forces
    • BCovalent bonds
    • CIonic bonds
    • DMetallic bonds
  5. 5.Which of the following statements explains why ammonia does not conduct electricity?

    Easy
    • AIt does not contain any free ions or free electrons
    • BIts ions are in a fixed position
    • CIt has delocalised electrons
    • DIt contains free electrons
  6. 6.The boiling point of nitrogen is very low even though the bond between atoms in a nitrogen molecule is very strong. Why?

    Medium
    • AOnly weak intermolecular forces need to be overcome
    • BThe covalent bonds are broken during boiling
    • CNitrogen molecules are very small
    • DNitrogen is a gas at room temperature
  7. 7.Which of the following elements can form covalent bonds?

    Easy
    • ACarbon
    • BSodium
    • CCalcium
    • DIron
  8. 8.Which of the following molecules contains a double bond?

    Easy
    • AOxygen (O2)
    • BHydrogen (H2)
    • CChlorine (Cl2)
    • DMethane (CH4)

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