Introduction To The Particulate Nature Of Matter

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Elements and Compounds

  • Elements are substances made from one kind of atom and cannot be chemically broken down into simpler substances.
  • Elements take part in chemical reactions in which new substances are made, often involving an energy change.
  • In chemical reactions, atoms combine in fixed ratios to give full outer shells of electrons, producing compounds.
  • Compounds are made from two or more elements chemically bonded together.
  • The properties of a compound can be quite different from the properties of the elements that form it (e.g., sodium chloride vs sodium and chlorine).

Ball-and-stick models of common elements and compounds

Ball-and-stick models of common elements and compounds

Mixtures

  • Mixtures contain more than one element or compound in no fixed ratio.
  • The components of a mixture are interspersed but not chemically combined.
  • The components of a mixture retain their own characteristic properties (e.g., oxygen in air still supports combustion).
  • A homogeneous mixture has uniform composition and properties throughout (e.g., air, bronze).
  • A heterogeneous mixture has non-uniform composition, so its properties are not the same throughout (e.g., concrete, orange juice with pulp).
  • It is often possible to see the separate components in a heterogeneous mixture, but not in a homogeneous mixture.

Particle diagram showing elements, compounds and mixtures

Particle diagram showing elements, compounds and mixtures

Separating Mixtures: Solubility and Filtration

  • Separation techniques take advantage of differences in physical properties such as boiling point, solubility, magnetism, or density.
  • Solvation is the process where solvent particles surround and attract solute particles; in water it is called hydration.
  • Filtration separates an undissolved (insoluble) solid from a liquid or solution using filter paper.
  • In filtration, the liquid that passes through is the filtrate and the solid left behind is the residue.
  • Filtration works because solid particles are too large to pass through the pores in the filter paper.
  • Vacuum filtration can be used for very fine solids that clog filter paper under gravity filtration; centrifugation can also separate solid–liquid mixtures.

Filtration apparatus

Filtration apparatus

Separating Mixtures: Crystallisation and Recrystallisation

  • Crystallisation separates a dissolved solid from a solution when the solid is more soluble in hot solvent than cold.
  • To crystallise, heat the solution gently to evaporate some solvent, then allow it to cool slowly until crystals form.
  • Do not boil to dryness, as this may prevent crystal formation; cool slowly to allow larger crystals to grow.
  • Recrystallisation purifies an impure solid by dissolving it in a minimum amount of hot solvent and allowing it to crystallise as the solution cools.
  • Impurities remain in the solvent when cooled, while the purified product crystallises.
  • Büchner filtration under reduced pressure is faster and more effective than gravity filtration for collecting crystals.

Crystallisation by evaporation and cooling

Crystallisation by evaporation and cooling

Separating Mixtures: Distillation and Chromatography

  • Simple distillation separates a solvent from a solute or a pure liquid from a mixture, based on differences in boiling point.
  • In simple distillation, the liquid with the lowest boiling point evaporates first, then its vapour is condensed and collected as the distillate.
  • Fractional distillation separates two or more miscible liquids with similar boiling points using a fractionating column (e.g., ethanol and water, crude oil).
  • Paper chromatography separates dissolved substances based on differences in solubility and adsorption to the paper.
  • In chromatography, substances more soluble in the solvent travel further; those more strongly adsorbed to the paper move more slowly.
  • The pattern of separated spots is called a chromatogram.
  • Magnetic separation uses differences in magnetic properties (e.g., removing iron filings from sulfur).

Paper chromatography

Paper chromatography

The Three States of Matter

  • Solids have a fixed shape and volume; particles are closely packed in a regular, ordered pattern and can only vibrate in place.
  • Liquids have a fixed volume but take the shape of their container; particles are close together but randomly arranged and can slide past one another.
  • Gases have no fixed shape or volume; particles are widely spaced, randomly arranged, and move quickly in all directions.
  • Particle motion in gases causes collisions, which generate pressure.
  • Density decreases from solid to liquid to gas due to increasing particle separation.
  • Particle energy increases from solid to liquid to gas.

Particle arrangements in solids, liquids and gases

Particle arrangements in solids, liquids and gases

Changes of State

  • State changes are physical changes and are reversible; they involve energy transfer but do not alter the chemical identity of the substance.
  • Melting: solid → liquid; Freezing: liquid → solid.
  • Vaporisation: liquid → gas, including boiling (throughout the liquid at a specific temperature) and evaporation (only at the surface, below boiling point).
  • Condensation: gas → liquid; Sublimation: solid → gas; Deposition: gas → solid.
  • Energy is always required to overcome intermolecular forces, so melting, vaporisation, and sublimation are endothermic.
  • Energy is released when particles come closer, so freezing, condensation, and deposition are exothermic.
  • State symbols in equations: (s) solid, (l) liquid, (g) gas, (aq) aqueous.

Changes of state

Changes of state

Average Kinetic Energy and Temperature

  • Temperature is a measure of the average kinetic energy (Ek) of the particles in a substance.
  • The Kelvin (K) is the SI unit of temperature; temperature in Kelvin is directly proportional to average kinetic energy.
  • The higher the temperature, the faster the particles move on average.
  • At the same temperature, all gases have the same average kinetic energy, but lighter gases move faster and heavier gases move slower.
  • Convert Celsius to Kelvin: T(K) = T(°C) + 273.15; Kelvin to Celsius: T(°C) = T(K) − 273.15.
  • 0 K (absolute zero) is the temperature at which particles have no kinetic energy.

Interpreting Heating Curves

  • During heating of a solid, particles vibrate more as they gain kinetic energy, so temperature increases.
  • During melting (solid → liquid), energy is used to overcome intermolecular forces, not to increase kinetic energy, so temperature remains constant.
  • During heating of a liquid, particles move more freely and gain kinetic energy, so temperature rises again.
  • During boiling (liquid → gas), energy goes into overcoming intermolecular forces, so temperature remains constant.
  • After boiling, the substance is a gas; particles move rapidly and have the highest average kinetic energy, so temperature increases again.
  • Observations: melting loses shape but volume remains constant; boiling forms bubbles throughout; condensation forms droplets on cooler surfaces; freezing regains rigid shape; sublimation solid disappears directly into vapour.

A heating curve

A heating curve

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Xem trước miễn phí — 8 trên 61 câu hỏi. Đăng ký để xem tất cả.
  1. 1.Which equation represents deposition?

    Medium
    • AI₂(g) → I₂(s)
    • BI₂(s) → I₂(g)
    • CH₂O(g) → H₂O(l)
    • DCO₂(s) → CO₂(g)
  2. 2.Which statements about mixtures are correct? (select all that apply)

    Medium
    • AMixtures can contain elements and compounds.
    • BThe components of a mixture must be in the same state.
    • CThe components of a mixture keep their own properties.
    • DMixtures have a fixed ratio of components.
  3. 3.Which of the following is a heterogeneous mixture?

    Medium
    • AAn aqueous solution of copper(II) chloride
    • BAn alloy of iron, carbon and chromium
    • CA mixture of sulfur and potassium chloride
    • DA mixture of ammonia, hydrogen sulfide and methane gases
  4. 4.The components of a mixture are chemically combined.

    Easy

    True or false?

  5. 5.Match each change of state with its correct description.

    Medium
    • Melting
    • Freezing
    • Sublimation
    • Deposition
    • solid to liquid
    • liquid to solid
    • solid to gas
    • gas to solid
  6. 6.Which statement is correct about recrystallisation when purifying a solid?

    Medium
    • AThe solid must be insoluble in the hot solvent
    • BThe impurities will remain in the solvent when cooled
    • CThe yield of product is the same after recrystallisation
    • DThe solvent is in excess during recrystallisation
  7. 7.Which of the following mixtures cannot be classified as homogeneous?

    Medium
    • ASalt solution
    • BBrass
    • COrange juice that has been filtered
    • DConcrete
  8. 8.Which of the following are examples of homogeneous mixtures? (select all that apply)

    Medium
    • AAir
    • BBronze
    • CConcrete
    • DOrange juice with pulp
    • ESalt solution

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