Radioactive Decay

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Isotopes

  • Isotopes are nuclei with the same number of protons but different numbers of neutrons.
  • An isotope of an element has a fixed proton number (Z) but a different nucleon number (A).
  • Some isotopes are unstable due to an imbalance of neutrons and protons, causing them to decay and emit radiation.
  • Unstable isotopes can decay over timescales ranging from a few nanoseconds to 100,000 years.
  • Isotopic data refers to the relative amounts of different isotopes of an element in a substance.
  • The relative atomic mass of an element is calculated using the masses and abundances of its naturally occurring isotopes.
  • The percentage abundance of isotopes in a sample can be measured using a mass spectrometer.

Isotopes of hydrogen

Isotopes of hydrogen

Radioactive Decay

  • Radioactive decay is the spontaneous disintegration of a nucleus to form a more stable nucleus, emitting an α, β or gamma particle.
  • Radioactive decay is a random process: the exact time of decay of a nucleus cannot be predicted.
  • Each nucleus has a constant probability of decaying in a given time.
  • Radioactive decay is spontaneous: it cannot be influenced by environmental factors such as temperature, pressure or chemical conditions.
  • The random nature of decay is demonstrated by fluctuations in the count rate of a Geiger-Muller (GM) tube.
  • With large numbers of nuclei, the behaviour of the group can be statistically predicted.

Alpha decay

Alpha decay

Background Radiation

  • Background radiation is the ionising radiation present in the environment.
  • Natural sources include radon gas from rocks and buildings, cosmic rays from space, carbon-14 in biological material, and radioactive material in food and drink.
  • In the UK, radon gas is the largest proportion of background radiation.
  • Artificial sources include nuclear medicine, nuclear waste, nuclear fallout and nuclear accidents.
  • Background radiation must be accounted for by measuring the count rate with no source present and subtracting it from readings with the source present.
  • The corrected count rate is the count rate of a source minus the background count rate.
  • Accuracy of count rate measurements can be improved by repeating readings and taking averages, and by taking readings over a long period of time.

Alpha, Beta & Gamma Particles

  • An α (α) particle is a high-energy helium nucleus containing 2 protons and 2 neutrons; it has mass 4u and charge +2e.
  • A β-minus (β⁻) particle is a high-energy electron with mass 0.0005u and charge −1e; it is emitted when a neutron turns into a proton.
  • A β-plus (β⁺) particle is a high-energy positron with mass 0.0005u and charge +1e; it is emitted when a proton turns into a neutron.
  • Gamma (γ) radiation is high-energy electromagnetic radiation emitted by nuclei losing excess energy; it has no charge and no mass.
  • α particles are highly ionising and have low penetrating power; they can be stopped by a sheet of paper.
  • β particles are moderately ionising and penetrating; they can be stopped by a few millimetres of aluminium foil.
  • Gamma radiation is weakly ionising and highly penetrating; its intensity can be reduced by several centimetres of lead or metres of concrete.
  • In electric and magnetic fields, α and β particles are deflected, while gamma radiation is not.

Penetrating power of alpha, beta and gamma radiation

Penetrating power of alpha, beta and gamma radiation

Radioactive Decay Equations

  • α decay: nucleon number decreases by 4, proton number decreases by 2. General equation: ᴬZ X → ᴬ⁻⁴Z−2 Y + ⁴₂α.
  • β-minus decay: nucleon number stays the same, proton number increases by 1. General equation: ᴬZ X → ᴬZ+1 Y + ⁰−1β + ν̄e.
  • β-plus decay: nucleon number stays the same, proton number decreases by 1. General equation: ᴬZ X → ᴬZ−1 Y + ⁰+1β + νe.
  • Electron capture: a proton combines with an orbiting electron to form a neutron and a neutrino; proton number decreases by 1, nucleon number stays the same.
  • Gamma emission: proton number and nucleon number remain unchanged; it usually follows α or β decay.
  • An electron neutrino (νe) is produced during β⁺ decay; an electron antineutrino (ν̄e) is produced during β⁻ decay.
  • Decay modes are determined by the type of instability: too many neutrons → β⁻; too many protons → β⁺ or electron capture; too many nucleons → α; too much energy → γ.

Beta decay

Beta decay

Activity & Half-Life

  • Activity is the number of nuclei that decay per unit time, measured in becquerels (Bq); 1 Bq = 1 decay per second.
  • Half-life is the time taken for half the undecayed nuclei to decay, or for the activity to fall to half its original value.
  • Different isotopes have different half-lives, ranging from fractions of a second to billions of years.
  • The proportion of an isotope remaining after n half-lives is (1/2)ⁿ.
  • After 1 half-life, 50% remains; after 2, 25%; after 3, 12.5%; after 4, 6.25%.
  • To find half-life from a graph, determine the time for the activity to halve from its initial value.
  • The half-life is constant for a particular isotope.

A half-life graph showing activity falling from A0 to A0/2 to A0/4

A half-life graph showing activity falling from A0 to A0/2 to A0/4

Applications of Radioactivity

  • When selecting a radioactive isotope for use, consider its penetrating power and half-life.
  • Carbon dating: carbon-14 has a half-life of about 5730 years; it is used to date samples between 500 and 60,000 years old.
  • Uranium-lead dating: uranium-238 decays to lead-206 with a half-life of 4.5 billion years; used to determine the age of rocks and the Earth.
  • Detecting leaks in underground pipes uses a gamma emitter (e.g. sodium-24) because gamma radiation can penetrate several metres of ground.
  • Controlling thickness of materials uses β radiation (e.g. for aluminium foil) because α would be absorbed and gamma would pass through undetected.
  • Smoke detectors contain americium-241, an α emitter; α particles ionise air, allowing a small current that is disrupted by smoke.
  • Sterilising equipment uses gamma radiation (e.g. cobalt-60) because it can penetrate sealed plastic bags.

Mass Defect & Nuclear Binding Energy

  • Mass defect is the difference between the mass of a nucleus and the sum of the masses of its individual nucleons.
  • Binding energy is the energy required to separate a nucleus into its constituent protons and neutrons.
  • Mass and energy are related by Einstein's equation: ΔE = Δmc².
  • The binding energy of a nucleus can be calculated using the mass defect: E = Δm c².
  • Binding energy per nucleon is the binding energy of a nucleus divided by the number of nucleons in the nucleus.
  • A higher binding energy per nucleon indicates a more stable nucleus.
  • The mass defect for helium-4 is about 5.04 × 10⁻²⁹ kg, giving a binding energy of about 28 MeV.

Binding Energy per Nucleon Curve

  • The binding energy per nucleon curve plots binding energy per nucleon against nucleon number.
  • The curve rises steeply for light nuclei, peaks around iron-56 (nucleon number ~56), and gradually decreases for heavier nuclei.
  • The peak represents the most stable nuclei, with a binding energy per nucleon of about 8.8 MeV.
  • Nuclei with lower binding energy per nucleon are less stable and can undergo fusion (light nuclei) or fission (heavy nuclei) to become more stable.
  • The graph helps explain why energy is released in nuclear fusion and fission.

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Câu hỏi luyện tập

Xem trước miễn phí — 8 trên 61 câu hỏi. Đăng ký để xem tất cả.
  1. 1.Which of the following is the correct definition of isotopes?

    Easy
    • ANuclei that have the same number of protons but different numbers of neutrons
    • BNuclei that have the same number of neutrons but different numbers of protons
    • CNuclei that have the same number of protons and the same number of neutrons
    • DNuclei that have the same mass number but different proton numbers
  2. 2.Which of the following statements about radioactive decay is correct?

    Medium
    • AIt is spontaneous and random.
    • BIt is spontaneous but not random.
    • CIt is random but can be influenced by temperature.
    • DIt can be affected by chemical conditions.
  3. 3.Which of the following are natural sources of background radiation? (select all that apply)

    Medium
    • ARadon gas from rocks and buildings
    • BCosmic rays from space
    • CNuclear fallout from nuclear weapons
    • DCarbon-14 in biological material
    • ENuclear medicine
  4. 4.An α particle is a high-energy helium nucleus containing 2 protons and 2 neutrons.

    Easy

    True or false?

  5. 5.Match each type of radiation with its correct description.

    Medium
    • α particle
    • β-minus particle
    • Gamma radiation
    • High-energy electron
    • High-energy electromagnetic radiation
    • High-energy helium nucleus
  6. 6.Which of the following correctly describes the charge and mass of an electron neutrino?

    Easy
    • ACharge zero, mass negligible
    • BCharge +1e, mass 0.0005 u
    • CCharge -1e, mass 0.0005 u
    • DCharge zero, mass 1 u
  7. 7.A radioactive sample has a half-life of 10 days. What is the approximate percentage of the sample remaining after 25 days?

    Medium
    • A20%
    • B19%
    • C16%
    • D15%
  8. 8.Which of the following is the correct definition of half-life?

    Easy
    • AThe time taken for half the undecayed nuclei to decay
    • BThe time taken for all the nuclei to decay
    • CThe time taken for the activity to double
    • DThe time taken for the number of nuclei to halve in size

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