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Atomic Structure & The Periodic Table

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课程笔记

Elements, Compounds & Mixtures

  • Element: substance made of atoms with the same number of protons; cannot be split chemically.
  • Compound: pure substance of two or more elements chemically combined; cannot be separated by physical means.
  • Mixture: combination of substances not chemically combined; separable by physical methods (e.g., filtration).
  • Examples: element = copper; compound = CO₂; mixture = sand and water.

Particle diagram showing elements, compounds and mixtures

Particle diagram showing elements, compounds and mixtures

Atomic Structure

  • Atoms consist of protons, neutrons (in nucleus) and electrons (in shells).
  • Proton: relative mass 1, charge +1; Neutron: relative mass 1, charge 0; Electron: relative mass 1/1840, charge -1.
  • Atomic number (Z) = number of protons; determines element and equals electrons in neutral atom.
  • Mass number (A) = total protons + neutrons; also called nucleon number.
  • Number of neutrons = mass number – atomic number.

The structure of the carbon atom

The structure of the carbon atom

Electronic Configuration

  • Electrons occupy shells (energy levels); first shell holds 2, second 8, third 8 (simplified).
  • Electronic configuration lists electrons per shell, e.g., carbon = 2,4.
  • Outermost shell (valence shell) determines chemical properties; full outer shell = stable (noble gas).
  • Number of occupied shells = Period number; number of outer electrons = Group number (for Groups I–VII).
  • Ions: e.g., Na⁺ has configuration 2,8 (lost one electron).

Bohr model of a sodium atom showing nucleus with 11 protons and 12 neutrons, and electron shells 2,8,1.

Na — Bohr model (2,8,1)11p12n

Isotopes

  • Isotopes: same element, same number of protons, different number of neutrons.
  • Isotopes have identical chemical properties (same outer electrons) but different physical properties (mass).
  • Notation: e.g., carbon-14 or ¹⁴C.

The structure of a hydrogen-2 (deuterium) atom

The structure of a hydrogen-2 (deuterium) atom

Relative Atomic Mass (Extended)

  • Relative atomic mass (Aᵣ) = weighted average mass of all isotopes compared to 1/12 mass of carbon-12.
  • Formula: Aᵣ = (Σ(% abundance × mass)) / 100.
  • Example: rubidium: (72×85 + 28×87)/100 = 85.6.

Periodic Table & Groups

  • Elements in same Group have same number of outer electrons and similar chemical properties.
  • Noble gases (Group 0/VIII) have full outer shells and are unreactive.
  • Group number for Groups I–VII equals number of outer electrons.
  • Period number equals number of occupied electron shells.

The Periodic Table showing groups and periods

The Periodic Table showing groups and periods

幻灯片

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练习题

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  1. 1.Which option correctly describes the relative charges and masses of the subatomic particles?

    Easy
    • AProton +1, neutron 0, electron -1; relative mass of proton 1, neutron 1, electron 0.00054
    • BProton +1, neutron 0, electron -1; relative mass of proton 0.00054, neutron 1, electron 0
    • CProton 0, neutron +1, electron -1; relative mass of proton 1, neutron 1, electron 0.00054
    • DProton +1, neutron 0, electron 0; relative mass of proton 1, neutron 1, electron 0.00054
  2. 2.The atomic number of element Q is 9 and its mass number is 19. In which group of the Periodic Table should element Q be placed?

    Easy
    • AGroup 0
    • BGroup I
    • CGroup VII
    • DGroup II
  3. 3.The diagram shows the atomic structure of an element. Which element is it?

    Easy
    ? — Bohr model (2,2)4p5n
    • ACarbon
    • BBeryllium
    • COxygen
    • DBoron
  4. 4.Which two atoms are isotopes?

    Medium
    • AQ and S
    • BQ and T
    • CR and T
    • DR and S
  5. 5.Which of the following statements is correct?

    Easy
    • AElements contain different atoms
    • BCompounds consist of elements that are not chemically combined
    • CMixtures consist of elements that are chemically combined
    • DA mixture can contain elements and compounds
  6. 6.Which statement about carbon is correct?

    Medium
    • AIt has 4 electron shells.
    • BIt has 2 outer shell electrons.
    • CIt has 12 nucleons.
    • DIt has an electron configuration of 2,8,2.
  7. 7.Two atoms, X and Y can be represented as shown: ³₇X and ³₈Y. Which row is correct for both atoms?

    Medium
    • Aelectron configuration of X: 2,1; electron configuration of Y: 2,1; Is Y an isotope of X? Yes
    • Belectron configuration of X: 2,1; electron configuration of Y: 2,6; Is Y an isotope of X? Yes
    • Celectron configuration of X: 2,5; electron configuration of Y: 2,1; Is Y an isotope of X? No
    • Delectron configuration of X: 2,5; electron configuration of Y: 2,6; Is Y an isotope of X? No
  8. 8.Element X contains 12 of each sub-atomic particle. What is the correct Group number for element X?

    Medium
    • AGroup 0
    • BGroup I
    • CGroup VII
    • DGroup II

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