Heating and cooling curves
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课程笔记
Heating and Cooling Curves
- A heating curve shows how temperature changes as a substance is heated.
- A cooling curve shows how temperature changes as a substance cools.
- For a pure substance, temperature remains constant during a state change (melting or boiling).
- For an impure substance, melting and boiling occur over a range of temperatures.
Pure vs Impure Substances
- A pure substance is made from only one element or compound.
- An impure substance contains more than one element or compound (has impurities).
- Pure substances have a single, sharp melting/boiling point; impure substances melt/boil over a range.
Internal Energy
- Internal energy is the total energy stored in the particles of a substance.
- It consists of kinetic energy (movement) and potential energy (bonds/forces) stores.
- As thermal energy is transferred to a substance, its internal energy increases.
Changes During Heating
- When temperature rises, the kinetic energy of particles increases.
- In a solid, particles vibrate more as temperature increases.
- During melting, bonds break and temperature stays constant; potential energy increases.
- The thermal energy absorbed during a state change is called latent heat (from Latin for 'hidden').
- In liquids and gases, particles move faster as temperature rises.
Changes During Cooling
- As a gas cools, particles slow down and kinetic energy decreases.
- During condensation, bonds form and temperature stays constant; potential energy decreases.
- During freezing, bonds form and temperature stays constant; potential energy decreases.
Key Points
- Temperature remains constant during state changes (melting, boiling, freezing, condensing).
- The kinetic energy of particles changes only when temperature changes.
- The potential energy of particles changes only during state changes.
- Internal energy always increases when heating and decreases when cooling.
Particle arrangement in solid, liquid, and gas. In solids, particles vibrate in fixed positions; in liquids, they slide past each other; in gases, they move rapidly and are far apart.
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练习题
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1.What is a pure substance?
Easy- AA substance made from only one element or compound
- BA substance that contains no impurities
- CA substance that has a fixed melting point
- DAll of the above
2.What is internal energy?
Easy- AThe total kinetic energy of particles
- BThe total potential energy of particles
- CThe sum of the kinetic and potential energy stores of particles
- DThe energy transferred to a substance when heated
3.During which process does the temperature of a pure substance remain constant?
Easy- AHeating a solid
- BMelting and boiling
- CCooling a gas
- DHeating a liquid
4.What happens to the kinetic energy of particles when a solid is heated and its temperature rises?
Easy- AIt decreases
- BIt stays the same
- CIt increases
- DIt is converted to potential energy
5.Which statement about the cooling curve of a pure substance is correct?
Medium- ATemperature decreases at a constant rate throughout
- BTemperature remains constant during condensation and freezing
- CThe gas phase has the highest temperature at the start
- DThe curve is identical to the heating curve
6.An impure substance melts over a range of temperatures. What does this indicate?
Medium- AThe substance has a high specific heat capacity
- BThe substance contains more than one element or compound
- CThe substance is a pure compound
- DThe substance is in the gas phase
7.What happens to the potential energy of particles during melting?
Medium- AIt decreases
- BIt remains constant
- CIt increases
- DIt is converted to kinetic energy
8.On a heating curve for a pure substance, which section shows an increase in kinetic energy without a change in state?
Medium- AThe horizontal plateau
- BThe sloping line before a plateau
- CThe sloping line after a plateau
- DBoth sloping sections
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