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Thermal Properties And Temperature

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Notes de leçon

Thermal Expansion

  • When a material is heated at constant pressure, its temperature increases, volume increases (expands), and density decreases.
  • Expansion occurs because molecules gain kinetic energy, move/vibrate faster, and push each other apart.
  • For equal temperature rise, gases expand most, solids least, and liquids in between.
  • Liquid-in-glass thermometers use thermal expansion: liquid in bulb expands into narrow capillary tube; scale measures temperature.
  • Temperature-activated switches use a bimetallic strip (two metals with different expansion rates) that bends when heated to close a circuit.
  • Unwanted expansion can cause buckling in railway tracks, roads, and bridges; expansion gaps are built in to allow safe expansion.

Thermal expansion diagram

Thermal expansion diagram

Melting & Boiling

  • Fixed points of pure water: melting point = 0 °C, boiling point = 100 °C (at atmospheric pressure).
  • During a change of state (melting/boiling), temperature remains constant even though thermal energy is added or removed.
  • Added energy goes into the potential store (overcoming intermolecular forces), not the kinetic store, so temperature stays constant.
  • Melting: solid → liquid; particles gain ability to flow but remain close together.
  • Boiling: liquid → gas; intermolecular forces are completely overcome; bubbles form throughout the liquid.
  • Condensation (gas → liquid) and solidification (liquid → solid) release energy; temperature stays constant during the change.

Heating curve showing changes of state

Heating curve showing changes of state

Evaporation

  • Evaporation is a change of state from liquid to gas that occurs at any temperature and only from the surface.
  • More energetic molecules near the surface escape, reducing the average kinetic energy of the remaining liquid → cooling effect.
  • Rate of evaporation increases with higher temperature, larger surface area, and greater air movement (wind/fan).
  • Boiling vs evaporation: boiling occurs at the boiling point throughout the liquid; evaporation occurs at any temperature only at the surface.

Evaporation of liquid molecules

Evaporation of liquid molecules

Liquid-in-Glass Thermometer (Extended Tier)

  • Sensitivity increases if the capillary tube diameter is reduced (same volume change gives longer liquid column) or if the bulb volume is increased (more liquid expands further).
  • Range is affected by the length of the capillary tube and the amount of liquid; a smaller bulb (less mercury) reduces the range because less expansion occurs.

Liquid-in-glass thermometer

Liquid-in-glass thermometer

Diapos

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Questions d'entraînement

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  1. 1.State the fixed point on the Celsius scale for the melting point of pure water.

    Easy
    • A0
    • B2
    • C-1
    • D1
  2. 2.State the fixed point on the Celsius scale for the boiling point of pure water.

    Easy
    • A120
    • B90
    • C110
    • D100
  3. 3.Equal volumes of steel, oil and hydrogen are heated from 20 °C to 60 °C. Which substance has the greatest increase in volume?

    Medium
    • Asteel
    • Boil
    • Chydrogen
    • Dall increase by the same amount
  4. 4.State the temperature reading on a liquid-in-glass thermometer that shows the liquid level exactly at the 20 °C mark.

    Easy
  5. 5.State the temperature range of a liquid-in-glass thermometer that measures from -10 °C to 110 °C.

    Easy
  6. 6.Describe, in terms of molecules, what happens when a liquid evaporates.

    Medium
  7. 7.State two changes in the weather that help wet clothes to dry more quickly.

    Easy
  8. 8.Explain, in terms of molecules, how thermal expansion takes place in a liquid.

    Medium

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