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Properties of substances

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Lesson notes

What is a Substance?

  • A **substance** is a unique form of matter with constant chemical composition and characteristic properties.
  • Substances can be **elements** (e.g., diamond, a form of carbon) or **compounds** (e.g., water H₂O, table salt NaCl).
  • If two or more substances mix without reacting, they form a **mixture** (e.g., air, salt water).
  • A **pure substance** is a single element or compound, not mixed with any other substance.

Physical Properties

  • **Physical properties** can be observed or measured without changing the substance's identity.
  • Examples: melting point, boiling point, density, color, hardness, and electrical conductivity.
  • Pure water boils at **100 °C** (212 °F) at standard pressure – a characteristic physical property.
  • Substances can change **state** (solid, liquid, gas) without altering their chemical composition.

Chemical Properties

  • **Chemical properties** describe how a substance reacts with other substances to form new substances.
  • Examples: flammability, reactivity with acid, ability to rust or tarnish.
  • A chemical reaction produces one or more **new substances** with different properties.
  • **Inert** substances (e.g., noble gases) do not readily undergo chemical reactions.

Using Properties to Identify Substances

  • Every pure substance has a unique set of characteristic properties that can be used to identify it.
  • Measuring **melting point** or **boiling point** is a common way to test purity – pure substances melt/boil at sharp temperatures.
  • If a sample has a different boiling point than expected, it may be impure or a different substance.
  • Property data can also show whether a chemical reaction has occurred (new properties appear).

Law of Constant Composition

  • The **law of constant composition** states that a given compound always contains the same elements in the same proportion by mass.
  • For water, the mass ratio of hydrogen to oxygen is always 1:8 (or 2:16).
  • This law was established by Joseph Proust in the late 1700s.
  • It distinguishes compounds from mixtures, where proportions can vary.

States of Matter

  • Substances can exist as **solids**, **liquids**, or **gases** (and plasma).
  • In a **solid**, particles are tightly packed in a fixed arrangement; they vibrate but do not move past each other.
  • In a **liquid**, particles are close but can slide past each other; the substance takes the shape of its container.
  • In a **gas**, particles are far apart and move freely; the substance fills the entire container.

Pure Substances vs. Mixtures

  • A **pure substance** has a fixed composition and distinct properties (e.g., distilled water).
  • A **mixture** contains two or more substances physically combined; its composition can vary.
  • Mixtures can be **homogeneous** (uniform, like salt water) or **heterogeneous** (not uniform, like sand and water).
  • Mixtures can be separated by physical means (filtration, distillation) without chemical reactions.

Examples of Substances

  • **Water (H₂O)** – two hydrogen atoms bonded to one oxygen atom; boils at 100 °C.
  • **Table salt (NaCl)** – ionic compound; high melting point, dissolves in water.
  • **Diamond** – pure carbon; extremely hard, high melting point.
  • **Refined sugar (C₁₂H₂₂O₁₁)** – organic compound; sweet taste, decomposes on heating.

Particle arrangement in solid, liquid, and gas states.

Particle arrangementSolidLiquidGas

Bohr model of a sodium atom, showing electron shells.

Na — Bohr model (2,8,1)11p12n

Slides

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Practice questions

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  1. 1.What is a chemical substance?

    Easy
    • AA unique form of matter with constant chemical composition and characteristic properties
    • BAny material that can be found on Earth
    • CA mixture of two or more elements
    • DA substance that can only exist as a solid
  2. 2.Which of the following is an example of a chemical substance?

    Easy
    • APure water (H2O)
    • BAir
    • CSeawater
    • DGranite
  3. 3.The law of constant composition states that:

    Easy
    • AAll samples of a compound have the same proportions by mass of the elements present
    • BAll mixtures have variable composition
    • CElements always combine in the same physical state
    • DThe composition of a compound changes with temperature
  4. 4.Which of the following is a characteristic property of pure water?

    Medium
    • AIt boils at 100°C at standard pressure
    • BIt is always a liquid
    • CIt conducts electricity well
    • DIt has a variable boiling point
  5. 5.What is the atomic ratio of hydrogen to oxygen in every molecule of pure water?

    Medium
    • A2:1
    • B1:2
    • C1:1
    • D2:2
  6. 6.Which of the following is NOT a chemical substance?

    Medium
    • ASeawater
    • BDiamond
    • CTable salt (NaCl)
    • DRefined sugar (C12H22O11)
  7. 7.Why are isomers considered distinct chemical substances even though they have the same composition?

    Hard
    • AThey have different arrangements of atoms, leading to different properties
    • BThey have different numbers of atoms
    • CThey are mixtures of different elements
    • DThey exist only in different phases
  8. 8.In geology, a mineral is defined as:

    Medium
    • AAn inorganic solid substance of uniform composition
    • BA mixture of two or more rocks
    • CAny naturally occurring liquid
    • DAn organic compound found underground

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