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Polymers

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Polymers: The Basics

  • Polymers are large molecules built from many smaller monomers.
  • Each monomer is joined to the next by covalent bonds.
  • Examples include poly(ethene), PVC, and nylon.

Monomers joining to form a polymer

Monomers joining to form a polymer

Addition Polymerisation

  • Addition polymerisation occurs in monomers containing a C=C double bond (alkenes).
  • The C=C bond breaks, allowing monomers to join into a long chain.
  • Only one product (the polymer) is formed.
  • Example: ethene monomers → poly(ethene).
  • The polymer contains only single bonds.

Poly(ethene) formed by addition polymerisation

Poly(ethene) formed by addition polymerisation

Naming Addition Polymers

  • Name = poly- + monomer name in brackets, e.g., propene → poly(propene).
  • The repeat unit shows the polymer structure.
  • To draw a repeat unit: change the C=C to a single bond, add continuation bonds at ends, and write a subscript n.

Repeat units of poly(ethene) and poly(chloroethene)

Repeat units of poly(ethene) and poly(chloroethene)

Deducing Monomer from Polymer

  • Identify the repeating unit in the polymer chain.
  • Change the single bond in the repeat unit to a double bond.
  • Remove the continuation bonds at each end to obtain the monomer.

Deducing the monomer from a poly(chloroethene) repeat unit

Deducing the monomer from a poly(chloroethene) repeat unit

Condensation Polymers (Extended Tier)

  • Formed when two different monomers link together with the removal of a small molecule, usually water.
  • Each monomer has two functional groups (one at each end).
  • The polymer and one water molecule per linkage are produced.

Nylon (Polyamide)

  • Made from a dicarboxylic acid (two -COOH groups) and a diamine (two -NH₂ groups).
  • An amide linkage forms with loss of water.
  • Structure can be shown using boxes for carbon chains.

Formation of a polyamide (nylon)

Formation of a polyamide (nylon)

PET (Polyester)

  • Made from a dicarboxylic acid and a diol (two -OH groups).
  • An ester linkage forms with loss of water.
  • PET is also known as terylene and used in synthetic fibres.

Formation of PET (a polyester)

Formation of PET (a polyester)

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Câu hỏi luyện tập

Xem trước miễn phí — 8 trên 56 câu hỏi. Đăng ký để xem tất cả.
  1. 1.Which of the following is a polymer?

    Easy
    • AEthene
    • BPoly(ethene)
    • CEthanol
    • DEthanoic acid
  2. 2.What is the name of the small molecule that links together to form a polymer?

    Easy
  3. 3.Fill in the blanks.

    Easy

    During addition polymerisation, the ____ bond in the monomer breaks and only ____ product is formed.

  4. 4.Condensation polymerisation produces only the polymer molecule as the product.

    Easy

    True or false?

  5. 5.Match each polymer type with its monomer functional groups.

    Medium
    • Nylon
    • PET
    • Poly(ethene)
    • Dicarboxylic acid and diamine
    • Dicarboxylic acid and diol
    • Alkene
  6. 6.What small molecule is removed during condensation polymerisation?

    Easy
  7. 7.Which of the following is a polyamide?

    Easy
    • APoly(ethene)
    • BNylon
    • CPET
    • DPVC
  8. 8.How many water molecules are released when 10 monomers of a dicarboxylic acid and 10 monomers of a diamine polymerise to form nylon? (Assume all monomers react completely.)

    Hard
    • A12
    • B11
    • C9
    • D10

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