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Rates of reaction

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課程筆記

What is Rate of Reaction?

  • Rate of reaction is how quickly a chemical reaction takes place.
  • It depends on the frequency of successful collisions between reacting particles.
  • A successful collision has enough energy and correct orientation to react.

Factors Affecting Rate of Reaction

  • Temperature: Higher temperature → particles move faster → more frequent and energetic collisions → faster rate.
  • Concentration/Pressure: Higher concentration or pressure → more particles in same volume → more collisions → faster rate.
  • Surface Area: Breaking solid into smaller pieces increases surface area to volume ratio → more collisions on surface → faster rate.
  • Catalyst: A substance that increases rate without being used up; provides an alternative pathway with lower activation energy.

Measuring Rate of Reaction

  • Change in mass: For reactions producing a gas, measure mass loss over time (e.g., magnesium + hydrochloric acid → hydrogen gas escapes).
  • Volume of gas: Collect gas in a gas syringe and measure volume produced over time.
  • Precipitation: Time how long for a precipitate to form (e.g., sodium thiosulfate + HCl → yellow sulfur; use a black cross to observe cloudiness).
  • Colour change: Time how long for a colour change to occur.

Example: Magnesium and Hydrochloric Acid

  • Reaction: Mg + 2HCl → MgCl₂ + H₂ (hydrogen gas produced).
  • Rate can be measured by mass loss (escaping hydrogen) or gas volume in a syringe.
  • Using magnesium powder (higher surface area) gives a faster rate than large pieces.

Example: Sodium Thiosulfate and Hydrochloric Acid

  • Reaction: Na₂S₂O₃ + 2HCl → 2NaCl + SO₂ + S + H₂O (yellow sulfur precipitate).
  • Place flask over a black cross; time until cross is no longer visible due to cloudiness.
  • Increasing concentration or temperature of HCl increases rate (faster precipitation).

Particle arrangement in solids, liquids, and gases. In solids, particles are closely packed in a regular pattern; in liquids, they are close but irregular; in gases, they are far apart and move randomly. Higher temperature increases particle speed and collision frequency.

Particle arrangementSolidLiquidGas

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練習題

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  1. 1.What is meant by the term 'rate of reaction'?

    Easy
    • AHow quickly a chemical reaction takes place
    • BThe amount of product formed in a reaction
    • CThe temperature at which a reaction occurs
    • DThe energy released during a reaction
  2. 2.Which of the following statements is true?

    Medium
    • AParticles at a higher temperature move more quickly.
    • BA catalyst is used up during a chemical reaction.
    • CBreaking a solid into smaller pieces decreases its surface area to volume ratio.
    • DThe rate of reaction does not depend on the frequency of successful collisions.
  3. 3.What is a catalyst?

    Easy
    • AA substance that increases the rate of reaction without being used up
    • BA substance that slows down a reaction
    • CA substance that is consumed in a reaction
    • DA substance that increases the activation energy
  4. 4.Which of the following methods can be used to measure the rate of a reaction that produces a gas?

    Medium
    • AMeasuring the change in mass
    • BObserving a colour change
    • CUsing a light sensor to detect precipitate formation
    • DTiming the appearance of a precipitate
  5. 5.In the reaction between sodium thiosulfate and hydrochloric acid, what is observed as the reaction proceeds?

    Easy
    • AA yellow sulfur precipitate forms, making the solution cloudy
    • BA colourless gas is produced
    • CThe solution turns blue
    • DThe mass of the reaction mixture increases
  6. 6.Increasing the concentration of a reactant increases the rate of reaction because:

    Medium
    • AThere are more particles in the same volume, leading to more frequent collisions
    • BThe particles move faster
    • CThe activation energy is lowered
    • DThe particles have more energy
  7. 7.Which of the following would increase the rate of reaction between magnesium and hydrochloric acid?

    Medium
    • AUsing magnesium powder instead of large pieces
    • BDecreasing the temperature
    • CUsing a more dilute hydrochloric acid
    • DUsing a larger volume of the same concentration of acid
  8. 8.In an experiment to measure the rate of reaction between magnesium and hydrochloric acid, which method would be most appropriate?

    Medium
    • AMeasuring the volume of hydrogen gas produced over time using a gas syringe
    • BObserving the colour change of the solution
    • CUsing a light sensor to detect precipitate formation
    • DMeasuring the increase in mass of the reaction mixture

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