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Organic Families

边玩边学

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课程笔记

Fossil Fuels & Fractional Distillation

  • Fossil fuels (coal, natural gas, petroleum) release heat energy when burned.
  • Petroleum (crude oil) is a mixture of hydrocarbons separated by fractional distillation.
  • Fractional distillation separates fractions by boiling point in a column with a temperature gradient (hot at bottom, cool at top).
  • Fractions include: refinery gas (heating/cooking), gasoline (car fuel), naphtha (chemicals), diesel (diesel engines), bitumen (road surfacing).
  • As chain length increases down the column, boiling point increases due to stronger intermolecular forces.

Fractional distillation of petroleum

Fractional distillation of petroleum

Alkanes

  • Alkanes are saturated hydrocarbons with only single C–C bonds and general formula CₙH₂ₙ₊₂.
  • They are colourless, generally unreactive due to strong single covalent bonds.
  • Complete combustion of alkanes produces CO₂ and H₂O (e.g., CH₄ + 2O₂ → CO₂ + 2H₂O).
  • First five members: methane (CH₄), ethane (C₂H₆), propane (C₃H₈), butane (C₄H₁₀), pentane (C₅H₁₂).

Butane, an alkane

Butane (C₄H₁₀) — displayed formulaHHHHHHHHHHCCCC

Alkenes & Cracking

  • Alkenes are unsaturated hydrocarbons with at least one C=C double bond and general formula CₙH₂ₙ.
  • The C=C bond makes alkenes more reactive than alkanes; it can open to form new bonds.
  • Cracking breaks long-chain alkanes into shorter alkanes, alkenes, and H₂ using high temperature (600–700 °C) and a catalyst (Al₂O₃ or SiO₂).
  • Example: decane → octane + ethene (C₁₀H₂₂ → C₈H₁₈ + C₂H₄).
  • Cracking increases supply of useful fuels (e.g., petrol) and produces alkenes for polymers.

But-1-ene, an alkene

But-1-ene (C₄H₈) — displayed formulaHHHHHHHHCCCCC=C doublebond

Test for Alkenes

  • Alkenes are identified by adding aqueous bromine (bromine water), which is orange.
  • Alkane: no colour change (remains orange).
  • Alkene: decolourises (orange → colourless) because bromine adds across the C=C bond.

Bromine water test for alkanes and alkenes

Bromine water test for alkanes and alkenes

Addition Reactions (Extended)

  • Addition reactions involve atoms adding across the C=C double bond, forming a single saturated product.
  • Alkene + bromine → dibromoalkane (e.g., ethene + Br₂ → 1,2-dibromoethane).
  • Alkene + hydrogen (with Ni catalyst) → alkane (e.g., ethene + H₂ → ethane).
  • Alkene + steam (with acid catalyst) → alcohol (hydration; e.g., ethene + H₂O → ethanol).

Addition reaction of ethene and bromine

Addition reaction of ethene and bromine

Alcohols

  • Alcohols contain the hydroxyl (–OH) functional group and have general formula CₙH₂ₙ₊₁OH.
  • First three: methanol (CH₃OH), ethanol (C₂H₅OH), propanol (C₃H₇OH).
  • Ethanol is used in alcoholic drinks, as a fuel, and as a solvent.
  • Ethanol undergoes complete combustion: C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O.

Ethanol, an alcohol

Ethanol (C₂H₆O) — displayed formulaHHHHHHCCOHydroxyl group–OH

幻灯片

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练习题

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  1. 1.What is the main constituent of natural gas?

    Easy
    • Aethane
    • Bpropane
    • Cmethane
    • Dbutane
  2. 2.State the general formula of the alkanes.

    Easy
  3. 3.Alkenes are saturated hydrocarbons.

    Easy

    True or false?

  4. 4.Complete the sentence.

    Easy

    The process of breaking down long-chain hydrocarbons into shorter, more useful molecules is called ____.

  5. 5.How many carbon atoms are in a molecule of butane?

    Easy
    • A3
    • B5
    • C4
    • D6
  6. 6.Which of the following is the product of the complete combustion of methane?

    Easy
    • Acarbon monoxide and water
    • Bcarbon dioxide and water
    • Ccarbon and hydrogen
    • Dcarbon dioxide and hydrogen
  7. 7.What colour change is observed when bromine water is added to an alkene?

    Easy
  8. 8.Cracking requires a high temperature of around 600–700 °C and a catalyst such as aluminium oxide.

    Medium

    True or false?

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