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Solids Liquids And Gases

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课程笔记

Kinetic Theory & States of Matter

  • The kinetic theory describes matter as tiny particles in constant motion.
  • Solids: particles packed closely in a fixed, regular pattern; vibrate in position; high density.
  • Liquids: particles close but randomly arranged; slide past each other; adopt container shape; medium density.
  • Gases: particles far apart, move randomly and quickly (~500 m/s); low density; easily compressed.
  • Particle energy increases from solid (low) → liquid → gas (highest).

Particle arrangement in solids, liquids, and gases

Changes of State

  • Melting: solid → liquid at a specific melting point; requires heat to increase particle kinetic energy.
  • Freezing: liquid → solid at the same temperature as melting point.
  • Boiling: liquid → gas at a specific boiling point; bubbles form throughout the liquid.
  • Evaporation: liquid → gas at the surface, below boiling point; faster with larger surface area and higher temperature.
  • Condensation: gas → liquid on cooling; particles lose energy and group together.
  • State changes are reversible (⇌).

The state changes

Heating & Cooling Curves (Extended)

  • A heating curve shows temperature vs. time as a substance is heated.
  • Horizontal sections indicate a change of state with no temperature change (energy used to overcome forces).
  • A cooling curve is the mirror image of a heating curve.

A heating curve

Pressure & Temperature in Gases

  • Gas pressure is caused by particles colliding with container walls.
  • Increasing temperature increases particle kinetic energy → more frequent collisions → volume expands if container flexible.
  • Increasing pressure (same number of particles in smaller volume) decreases volume; particles hit walls more often.
  • If pressure is too high, container may leak or explode.

Pressure increases as volume decreases

Diffusion

  • Diffusion: net movement of particles from high to low concentration due to random motion.
  • Occurs in liquids and gases; no energy input required; faster at higher temperatures.
  • Diffusion is faster in gases than liquids because gas particles have more kinetic energy.
  • Example: potassium manganate(VII) in water spreads until evenly coloured.

Diffusion of potassium manganate(VII) in water

Diffusion & Molecular Mass (Extended)

  • At the same temperature, gases with lower relative molecular mass diffuse faster.
  • Example: ammonia (Mᵣ = 17) diffuses faster than hydrogen chloride (Mᵣ = 36.5).
  • In a tube, NH₃ and HCl react to form NH₄Cl; the white ring forms closer to the HCl end.

Diffusion of ammonia and hydrogen chloride

幻灯片

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练习题

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  1. 1.Which statement about the arrangement of particles in a solid is correct?

    Easy
    • AParticles are far apart and move randomly
    • BParticles are close together and arranged randomly
    • CParticles are close together in a fixed regular pattern
    • DParticles are far apart and vibrate in fixed positions
  2. 2.Which statement about the movement of particles in a liquid is correct?

    Easy
    • AParticles vibrate about fixed positions
    • BParticles move around each other
    • CParticles move quickly in all directions
    • DParticles do not move
  3. 3.In a gas, the particles are far apart and move randomly.

    Easy

    True or false?

  4. 4.State the term for the change of state from a solid to a liquid.

    Easy
  5. 5.Water boils at 100 °C. What is the boiling point of water in Kelvin?

    Easy
    • A410
    • B373
    • C336
    • D447
  6. 6.Complete the sentence about diffusion.

    Easy

    Diffusion is the movement of particles from an area of ____ concentration to an area of ____ concentration.

  7. 7.Match each state of matter with its particle arrangement.

    Medium
    • Solid
    • Liquid
    • Gas
    • Randomly arranged
    • Regular arrangement
    • Randomly arranged
  8. 8.Ammonia (Mr = 17) and hydrogen chloride (Mr = 36.5) diffuse from opposite ends of a tube. Where does the white smoke of ammonium chloride form?

    Hard
    • AExactly in the middle of the tube
    • BCloser to the ammonia end
    • CCloser to the hydrogen chloride end
    • DAt both ends equally

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